There is no such feature out of the box . You need to write your own code for achieving it. something like
protected void ExporttoPDF_Click(object sender, EventArgs e)
{
Response.ContentType = "application/pdf";
Response.AddHeader("content-disposition", "attachment;filename=ExporttoPDF.pdf");
Response.Cache.SetCacheability(HttpCacheability.NoCache);
StringWriter sw = new StringWriter();
HtmlTextWriter hw = new HtmlTextWriter(sw);
this.Page.RenderControl(hw);
StringReader sr = new StringReader(sw.ToString());
Document pdfDoc = new Document(PageSize.A4, 10f, 10f, 100f, 0f);
HTMLWorker htmlparser = new HTMLWorker(pdfDoc);
PdfWriter.GetInstance(pdfDoc, Response.OutputStream);
pdfDoc.Open();
htmlparser.Parse(sr);
pdfDoc.Close();
Response.Write(pdfDoc);
Response.End();
}
Refer this