I am trying to add the Checked Out To column to my SharePoint library.
I can see the column in the Library Settings here:
But when I go to add the column in the library, it doesn't show up:
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I see the same behavior in modern experience of SharePoint library. So in this case, you can show the column in library view using old/classic experience way.
Follow below steps to add "Checked Out To" column to library view: