I have been trying for quite some time, but have not had any luck. I have on question and one question only.
Is it possible to add managed metadata to people within the Person or Group column?
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No, we could not add managed metadata to the Person or Group column.
As referred before, we could only associate the profile property with a managed metadata term set in User profile service application.
For more information, please refer to:
You can add your own properties to user profiles: