I plan to create an application with SharePoint Framework reads every hour term from TermSet and create the corresponding folder in a library, if it does not already exist.
Which type of component (WP, Ext, Lib) is best suited for this solution?
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Difference between spfx web part and extension:
Web parts allow you to create components that can be added by content editors as content on a page. Extensions add functionality to known areas of pages on an entire site or site collection, for example to add things in the header or footer of every page, or add menu options in a list toolbar. Extensions are often added by administrators.
You could use pnp js get terms: