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I'm working with SharePoint 2013 and SQL server 2014. Getting below exception while starting "User Profile Synchronization Service".

    User Profile Application Proxy failed to retrieve partitions from User Profile Application: Microsoft.Office.Server.UserProfiles.UserProfileApplicationNotAvailableException: UserProfileApplicationNotAvailableException_Logging :: UserProfileApplicationProxy.ApplicationProperties ProfilePropertyCache does not have ad1f9c65-4d27-4658-8a16-f9b7380a5619    
 at Microsoft.Office.Server.Administration.UserProfileApplicationProxy.get_ApplicationProperties()    
 at Microsoft.Office.Server.Administration.UserProfileApplicationProxy.get_PartitionIDs()    
 at Microsoft.Office.Server.Administration.UserProfileApplicationProxy.IsAvailable(SPServiceContext serviceContext)

Below are the some of the logs when filtered with category as User Profiles in ULS viewer:

User Profiles   cm6y    High    User Profile Application Proxy failed to retrieve partitions from User Profile Application: Microsoft.Office.Server.UserProfiles.UserProfileApplicationNotAvailableException: UserProfileApplicationNotAvailableException_Logging :: UserProfileApplicationProxy.ApplicationProperties ProfilePropertyCache does not have ad1f9c65-4d27-4658-8a16-f9b7380a5619     at Microsoft.Office.Server.Administration.UserProfileApplicationProxy.get_ApplicationProperties()     at Microsoft.Office.Server.Administration.UserProfileApplicationProxy.get_PartitionIDs()     at Microsoft.Office.Server.Administration.UserProfileApplicationProxy.IsAvailable(SPServiceContext serviceContext)
User Profiles   erx1    Medium  Provisioning service instance User Profile Synchronization Service.
User Profiles   erx2    Medium  The service instance User Profile Synchronization Service is successfully provisioned.
User Profiles   9i1s    Medium  UserProfileApplication.SynchronizeMIIS: Begin setup for 'User Profile Service App'.
User Profiles   9i1y    Medium  ILM Configuration: Validating account.
User Profiles   9i20    Medium  ILM Configuration: Validating the system groups
User Profiles   9i23    Medium  ILM Configuration: Setting up WMI
User Profiles   9i24    Medium  ILM Configuration: Setting required permissions
User Profiles   9i26    Medium  ILM Configuration: Create install config file
User Profiles   9i28    Medium  ILM Configuration: Update source project
User Profiles   9i29    Medium  ILM Configuration: Changing service account credentials
User Profiles   d3bo    Medium  ILM Configuration: Setting policy for service account
User Profiles   9i2a    Medium  ILM Configuration: Configuring database
User Profiles   9i1w    Medium  ILM Configuration: Error 'ERR_CONFIG_DB'.
User Profiles   9sip    High    UserProfileApplication.SynchronizeMIIS: Failed to configure MIIS post database, will attempt during next rerun. Exception: System.Configuration.ConfigurationErrorsException: ERR_CONFIG_DB     at Microsoft.Office.Server.UserProfiles.Synchronization.ILMPostSetupConfiguration.ValidateConfigurationResult(UInt32 result)     at Microsoft.Office.Server.UserProfiles.Synchronization.ILMPostSetupConfiguration.ConfigureMiisStage2()     at Microsoft.Office.Server.Administration.UserProfileApplication.SetupSynchronizationService(ProfileSynchronizationServiceInstance profileSyncInstance).   
User Profiles   9i1u    Medium  UserProfileApplication.SynchronizeMIIS: End setup for 'User Profile Service App'.

I have verified the following:

  1. User from which you are starting User Profile Synchronization Service has DBO access to Sync DB
  2. Same User also Local machine Admin on SharePoint Server where FIM service will run

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